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It is indeed a great privilege for me to speak today the November 4th on
the occasion of the celebration of the C. V. Raman Day under the auspices
of the Scientific Awareness Forum, Ernakulam (SAFE) as part of its Vigyan
Utsav at Kochi.I sincerely appreciate the gesture shown to me by its President,
Prof C.K.Rajan of CUSAT, and I hope and trust that I will not disappoint
the organizers and the ever watchful audience of this literate State.
2.
What is the celebrated Raman Effect ? To quote in the very simple description
of Prof Arul Das from his very recent text book " Molecular Structure
and Spectroscopy ", Prentice Hall, 2001,
Photons can interact with
molecules of matter in a number of ways. When they strike a solid or collection
of molecules, most of them are scattered elastically (Rayleigh scattering).
But a few ( one in a million) undergo inelastic scattering. These inelastically
scattered photons have frequencies lower and higher than the incident frequency.
This phenomenon, predicted in 1923 by Smekel and observed by C.V.Raman
in 1928 is referred to as Raman scattering.The lines on the low and high
frequency sides of the Rayleigh line are called Stokes and anti-Stokes
lines respectively.The scattered photons have frequency shifts ( 10 - 4000
per cm) characteristic of the vibrational or rotational energies
of the molecule.These weak lines of modified frequencies are generally
referred to as the Raman Spectrum and the frequency shift from the exciting
line as Raman shift ".
Advantages of Raman over
IR spectroscopy are the following :
The energy of interest
is generally 10-4000cm-1, requiring light of l 100mm to 2.5mm which presents
experimental problems with IR spectroscopy. This is easily achieved with
Raman.
1. It is harder to focus
with IR due to the large and varying wavelengths used in microIR. It is
very easy to focus using microRaman.
2. Water is a strong absorber
of IR so this rules out IR spectra of water or species dissolved in it.
Water presents no experimental problems in Raman experiments.
3. Raman spectral studies
are unaffected by powder particle sizes or shape.
4. In Raman studies the
dimensions of the particles are large compared to the wavelength of the
beam, ~0.5mm, so spectra are essentially discrete lines.
Obviously the discovery
of Raman Effect was of very great significance. Acclaimed internationally,
he was knighted in 1929, became Fellow of Royal Society in 1930 and to
no surprise the Nobel Prize in 1930 " For his work on the scattering
of light and for the discovery of the effect known after him". Undoubtedly
it also became a moment of great glory for our country.
To quote again Prof Arul
Das,
"The first Raman spectrum
of an organic compound was observed using sun as the source, a telescope
as the receiver and human eye as the detector.As the scattering efficiency
is proportional to the fourth power of frequency, one prefers to work with
a high frequency source. However to reduce fluorescence low frequency
is preferred. In the pre-laser days , the commonly used sources were the
435.8 nm blue and the 253.6 nm uv lines of the mercury vapour … with very
great disadvantages….With the discovery ( only) of lasers the situation
changed considerably".
And this heralded the
acclaimed Laser Raman Spectra without which much of present day research
in the field would not have been possible at all. In other words, Raman
Effect has become immortal in all sense of the word in scientific research.
When we bow our heads today in his honour , we honour all those scientists
and technologists who made Raman Effect an every day feasibility. It is
in this connection that I invite your attention the fact that whereas Raman
had discovered his effect and published extensively on the same in
very renowned journals such as Nature, Philosophical Transactions, etc,
he had also invented the first Raman Spectrometer, yet he did not resort
to patent the latter concurrently. A quick search of the world literature
indicates that there are over 90 patents for " Raman
Spectrometer". One of the latest ones is :
US Patent No. 6,275,285
on " Laser Verification and Authentication Raman Spectrometer (LVARS) detecting
the Stokes Anti-Stokes Emission".
Assigned to Wizard of
Ink & Co.(Tuscon, AZ), the patent describes the invention of an LVARS
" capable of performing analysis and verification and authentication of
the optical and electromagnetic properties of organic and inorganic molecules,
both natural as well as manufactured compounds".
In essence, invention
of new Raman spectrometers for new purposes has continued to be a discovery-cum
invention oriented R&D area of great interest even after its original
discovery seven decades ago ! It is an interesting thought indeed
that if Raman had also patented his first spectrometer ( this was not unusual,
as was done for the nuclear reactor by the Nobel laureates Fermi and Szilard
, the transistor by Shockley and his other two Nobel laureates colleagues
, the one for new explosives by Alfred Nobel himself , and so on) and his
institute either by itself or jointly with relevant electronics laboratories
had also steadily developed newer Raman instruments as part of extending
its studies to new areas of research, the Raman Research Institute at Bangalore
would have had the benefit of additional financial resources as was the
case with the Max Plank Institute at Mulheim with her Zeigler-Natta catalyst
! It is important to note that whereas there are over 500 Nobel Laureates
in science and technology, the US Hall of Fame has honoured over
150 "Patent Laureates" who through their inventions of new products
and processes have transferred the benefits of modern science and technology
for the welfare of mankind. These names include Luis Pasteur, Carl Djerassi,
Alexander Graham Bell, W.H.Carothers, Thoamas Alva Edison, Henry Ford,
Charles Goodyear, and so on.
4.
This brings us to the definitions of 'discovery' and 'invention'. As per
definitions of the celebrated Random House dictionary, discovery means
'get knowledge of' and invention means ' to create as a product of
one's own ingenuity or experimentation'.
Hence the reason that
the discovery of Raman Effect forms a publishable matter whereas the invention
of the Raman Spectrometer qualifies for and a product patent. Undoubtedly
if science as an invaluable product of human labour has to play its un-surpassing
role in human progress, scientific discoveries and inventions must go hand
in hand in total complimentary fashion.
5.
It is interesting that espousing a similar strategy the World Conference
on Science held in Budapest held on July 2, 1999 under the joint auspices
UNESCO and International Council for Science (ISCU) gave a Declaration
on Science and the Use of Scientific Knowledge . The main points are the
following.
a. Seeks active collaboration
from all the fields of scientific endeavor.
b. Science for knowledge;
knowledge for progress.
c. Science for peace.
d. Science for development.
e. National strategies
and international co-operation needed to achieve the above needs.
Obviously it is understood
that the Indian S&T programs also continues to follow essentially
the rules of international S&T programs tailor-made to meet the specific
political-economic-development needs - - systematic R&D programmes
resulting in discovering new theories and inventing new products and processes
of practical use and conversion of the priority products and processes
into commercial technologies for national development. Hence the reason
that patents and patenting practices also in turn form a very crucial element
of such an S&T strategy.
6.
Being a product of the celebrated Industrial Revolution and of modern science
and technology, the first law on patents and patenting practices was incidentally
enacted in her areas of control in India by the then East India Company
in 1856.This was successively modified along the UK practices and this
process was continued after 1947 by the newly independent nation in terms
of the comprehensive Indian Patents Act,1970.After entry to the WTO, the
government is now amending the 1970 Act to become TRIPS-compliant; soon
India will then enter into a New IPR Regime. What are the implications
of these amendments for Indian S&T , these form the rest of the
presentation.
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